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Method for experimental data processing concerning chemical reaction rates in low-atomic gases. (English. Russian original) Zbl 07264989
Comput. Math. Math. Phys. 60, No. 7, 1199-1207 (2020); translation from Zh. Vychisl. Mat. Mat. Fiz. 60, No. 7, 1239-1247 (2020).
Summary: A new method for joint processing of experimental data from various laboratories based on their approximation by the generalized Arrhenius law is proposed. The method is based on the construction of a system of functions that are orthogonal on a given set of points with arbitrary weights. As a result, the confidence intervals of the approximation coefficients can be estimated and the number of terms required for the approximation can be correctly determined. The performance of the method is demonstrated as applied to reactions of hydrogen combustion in air that are important at \(T < 1000\) K. High accuracy of reaction rate approximation is achieved.
MSC:
80A30 Chemical kinetics in thermodynamics and heat transfer
80A25 Combustion
80-05 Experimental work for problems pertaining to classical thermodynamics
86A08 Climate science and climate modeling
Software:
GRI-Mech 3.0
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